Besides DfE professional and production staff the following post holders are given pre-release access up to 24 hours before release

Secretary of State, Private Office
Parliamentary Under-Secretary of State (Schools), Private Office
Special Advisors, Private Office
Permanent Secretary, Private Office
Assistant Private Secretary to Nick Gibb, Private Office

Director General, Education Standards Directorate
Deputy Director, Accountability
Chief Executive, Standards and Testing Agency
Deputy Director, Test Operations, Standards and Testing Agency
Director, Data and Education Standards Analysis
Finance Business Partner, Standards and Testing Agency
Senior Media Officer
Media Officer
Deputy Director, Education Data Division
Deputy Director, Assessment Policy, Standards and Testing Agency
Head of Assessment Policy, Standards and Testing Agency

Chief Regulator, Ofqual
Executive Director for General Qualifications, Ofqual
Senior Manager, Stakeholder Relationships, Ofqual
Associate Director, Standards and Comparability, Ofqual

Programme Director, Pearson Education Ltd
Head of NCT Programme Delivery, Pearson Education Ltd
Press Officer, Pearson Education Ltd