Besides DfE professional and production staff the following post holders are given pre-release access up to 24 hours before release. 

Secretary of State, Private Office
Ministers of State, Private Office * 2
Special Adviser to SoS
Special Advisors, Private Office
Teacher in Residence, Private Office
Permanent Secretary, Private Office
Director General, ESD 
Director, Assessment, Curriculum, Qualification and Accountability
Deputy Director, Curriculum and Standards Division
Deputy Director, Qualifications and Curriculum Division
Deputy Director, Accountability and Flexible Resource Division
Deputy Director, Academies Operations and Strategy Division
Grade 6, Curriculum and Standards Division * 2
Grade 6, Inspection and Accountability Unit
Grade 6, GCSE and A level reform
Grade 6, Free Schools
Grade 7, Academies Operations and Strategy Division
Grade 7, Accountability
Grade 7, Free Schools * 2
Grade 7, Academies, IFDA
Head of Communications, Press Office
SEO, Press Office